Staff Profile
Professor Andrew Benniston
Head of School of Natural & Environmental Sciences; Professor of Photonic Energy Sciences
- Telephone: +44 (0) 191 208 5706
- Address:
School of Natural & Environmental Sciences
Room 2.04 Agriculture Building
Newcastle University
Newcastle upon Tyne
NE1 7RU
Background
Introduction
I graduated from the University of Warwick in 1984 with a 1st class honours degree in chemistry and stayed to carry out a PhD under the supervision of Professor Peter Moore working on the preparation and coordination chemistry of azamacrocycles. After a one year Royal Society Fellowship in the group of Dr Jean-Pierre Sauvage in Strasbourg, France I spent several years in Austin, Texas with Dr Tony Harriman at the Center for Fast Kinetics Research publishing several papers on photoactive rotaxane systems and photodynamic dyes based on merocyanine 540. In 1994 I joined the Chemistry Department at Glasgow University as a lecturer and continued studies into photoactive assemblies based on ruthenium complexes and using time-resolved resonance Raman to probe ultrafast reactions. In 2001 I joined the staff in the Department of Chemistry at Newcastle University and co-founded the Molecular Photonics Laboratory (MPL) and in 2011 was promoted to professor.
My main role in the MPL is concerned with the design and synthesis of multi-component supermolecules for fundamental studies in energy and/or electron transfer. A more recent aspect is applying the developed systems for photonic applications such as real-time monitoring of physical processes in nano-environments, solid-state luminescence pressure-sensitive materials, photochromic materials for data recording, and fluorescence sensors for biological imaging. The complexity of the molecular systems produced depends greatly on the problem to be addressed, but high purity and full structural characterisation are paramount.
Roles and Responsibilities
Head of School
Qualifications
- PhD University of Warwick
- BSc (hons) 1st Chemistry: University of Warwick
- FRSC, CChem
Previous Positions
- 1994-2001 Lecturer: University of Glasgow
- 1992-1994 Postdoctoral researcher: University of Texas at Austin
- 1991-1992 Postdoctoral researcher: University of Strasbourg
Memberships
Royal Society of Chemistry
Honours and Awards
- Royal Society postdoctoral fellowship (1991)
- Royal Society of Chemistry JWT Jones Travel Fellowship (1996)
- Royal Society Travel Grant (2010)
Languages
English & French
Informal Interests
Time Travel
Research
Research Interests
Our research interests cover many different aspects of photochemistry and over the past several years a number of publications have covered the synthesis and applications of BODIPY derivatives. Other systems include expanded acridinium dyes, pyrene dimers for triplet-triplet annihilation, fluorescent viscosity probes, reactive oxygen species (ROS) detectors and porphyrin derivatives for hydrogen production. As well as these studies projects have focused on mimicking the oxygen evolving complex in photosystem II and the magnetic properties of manganese complexes.
General themes
- Directional Electron Transfer
- Multidimensional Molecular Switches
- New Imaging Technology
- Photochromic Materials
- Synthesis and Spectroscopy of Fluorescent Dyes
Google Scholar https://scholar.google.co.uk/citations?user=6S8Yjp0AAAAJ&hl=en
Current Work
- Energy transfer in molecular systems
- Artificial enzymes
- Fluorescent probes
Research Roles
My role is to design new molecular systems, supervise their synthesis and full characterisation and couple this to spectroscopic measurements. A project with Professor Peter Andras (Napier University) is concerned with the synthesis and testing of new neuron imaging probes. Overseas collaborators include Professor Nikolai Tkachenko (Finland), Professor Hugh Burrows (Portugal), Professor Juan Bartolome (Spain) and Drs Giamberini/Reinac (Spain).
Postgraduate Supervision
The synthesis section of the Molecular Photonics Laboratory is currently supporting PhD and MChem students.
Esteem Indicators
- EPSRC College Member (2003-2005).
- Grant Reviewer: National Science Foundation (USA).
- Organiser: RSC Macrocycles and Supramolecular Chemistry Meeting (2005).
- Invited contributor to the "Encylopedia of Supramolecular Chemistry" (Eds J. Steed & J. Atwood)(2004).
- Invited contributor to the acclaimed book "Nanostructured Materials and Nanotechnology" (Ed H. S. Nalwa) (2001).
- Invited articles for Chemical Society Reviews (1996), (2004) and (2006).
- Invited review article for PCCP on Renewable Energy (2007 Front Cover Article) and ‘Instant Insight’ for Chemical Science.
- Co-organiser RSC one-day symposium on Renawable Energy at Glasgow University (2009).
- Invited perspective article for PCCP on BODIPY compounds (2009).
- Keynote speaker at ACS Meetings in San Francisco and Boston (2010).
- Coordinator FP7-PEOPLE-2009-IRSES Grant (2010-2013).
- Royal Society Travel Fellowship (2010).
- Contributor at Sixth International Conference on Porphyrins and Phthalocyanines (New Mexico, 2010).
- Invited speaker at Solar Prague (COST) Meeting (2011).
- Scientific Committee Member for Faraday Discussion on Artificial Photosynthesis (2011).
- International Scientific Committee for IUPAC Photochemistry Meeting(Portugal, 2012).
- Invited speaker XVII Conference on Physical Methods in Coordination and Supramolecular Chemistry (Moldova, 2012)
- Invited organiser/lecturer at the 4th International Conference and Exhibition on Analytical and Bioanalytical Techniques (Las Vegas, 2013).
- Keynote speaker at 5th International Conference on Analytical and Bioanalytical Techniques (Beijing, 2014).
- Keynote speaker at XVIII Conference on Physical Methods in Coordination and Supramolecular Chemistry (Moldova, 2015).
- H-index 40 (Google Scholar).
Funding
- 10 EPSRC grants
- 4 Nuffield Foundation grants
- 2 Leverhulme grants
- 1 Royal Society
- 1 Commercial Funding
- 1 Marie Curie IRSES
Patents
1 BoE
Teaching
Undergraduate Teaching
- NES 1403 Fundamentals of Inorganic Chemistry (Transition Metal Chemistry)
- NES 2403 Inorganic Chemistry (Inorganic Reaction Mechanisms)
- NES 8401 Advanced Problem Solving
Postgraduate Teaching
PhD and MChem project supervision
Publications
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Articles
- Waly SM, Benniston AC, Harriman A. Deducing the Conformational Space for an Octa-Proline Helix. Chemical Science 2024, 15(5), 1657-1671.
- James RD, Cucinotta F, Waddell PG, Benniston AC. Synthesis, structure and spectroscopic properties of BODIPY dyes incorporating the pentafluorosulfanylphenyl group. New Journal of Chemistry 2023, 47(17), 8451-8459.
- Benniston AC, Zeng L. Recent Advances in Photorelease Complexes for Therapeutic Applications. Dalton Transactions 2022, 51(11), 4202-4212.
- Waly SM, Karlsson JKG, Waddell PG, Benniston AC, Harriman A. Light-Harvesting Crystals Formed from BODIPY-Proline Biohybrid Conjugates: Antenna Effects and Excitonic Coupling. The Journal of Physical Chemistry Part A 2022, 126(9), 1530–1541.
- Benniston AC, Sirbu A, Tkachenko NV, Zeng L, Waddell PG, Botchway SW. Voltage-Induced Fluorescence Lifetime Imaging of a BODIPY Derivative in Giant Unilamellar Vesicles as Potential Neuron Membrane Mimics. Chemical Communications 2021, 94(57), 12631-12634.
- Zeng L, Sirbu D, Tkachenko N, Benniston AC. Autocatalytic photodegradation of [Ru(ii)(2,2′-bipyridine)2DAD]+ (DADH = 1,2-dihydroxyanthracene-9,10-dione) by hydrogen peroxide under acidic aqueous conditions. Dalton Transactions 2021, 50(22), 7640-7646.
- Cuzan-Munteanu O, Sirbu D, Giorgi M, Shova S, Gibson EA, Réglier M, Orio M, Martins L, Benniston AC. Neutral Lipophilic Palladium(II) Complexes and their Applications in Electrocatalytic Hydrogen Production and C-C Coupling Reactions. European Journal of Inorganic Chemistry 2020, 2020(10), 813-822.
- Zeng L, Sirbu D, Waddell PG, Tkachenko NV, Probert MR, Benniston AC. Hydrogen Peroxide Assisted Photorelease of an Anthraquinone-based Ligand from [Ru(2,2’-bipyridine)2(9,10-dioxo-9,10-dihydroanthracen-1-olate)]Cl in Aqueous Solution. Dalton Transactions 2020, 38, 13243-13252.
- Choo YSL, Giamberini M, Reina JA, Waddell PG, Benniston AC. Functionalized Fluorescent Terephthalate Monomers and their Attempted Polyester Formation. Organic & Biomolecular Chemistry 2020, 18(42), 8735-8745.
- Choo YSL, Waddell PG, Benniston AC. Synchronized “Click” and Templated Synthesis of a Fluorescent Pyrene Crown Ether. European Journal of Organic Chemistry 2019, 2019(14), 2560-2565.
- Bozdemir OA, Al-Sharif HHT, McFarlane W, Waddell PG, Benniston AC, Harriman A. Solid‐State Emission from Mono‐ and Bichromophoric Boron Dipyrromethene (BODIPY) Derivatives and Comparison with Fluid Solution. Chemistry - A European Journal 2019, 25(68), 15634-15645.
- Benniston AC, Sirbu D, Wales R, Geary DR, Waddell PG. Rosindone Revisited: A Computational and Photophysical Study of 7-Phenylbenzo[a]phenazine-5(7H)-one (PBP). Photochemical & Photobiological Sciences 2019, 18(1), 140-147.
- Sirbu D, Luli S, Leslie J, Oakley F, Benniston AC. Enhanced in vivo Optical Imaging of the Inflammatory Response to Acute Liver Injury in C57BL/6 Mice using a Highly Bright Near-Infrared BODIPY Dye. ChemMedChem 2019, 14(10), 995-999.
- Sirbu D, Zeng L, Waddell PA, Benniston AC. An unprecedented oxidised julolidine-BODIPY conjugate and its application in real-time ratiometric fluorescence sensing of sulfite. Organic and Biomolecular Chemistry 2019, 17(31), 7360-7368.
- Sirbu D, Woodford OJ, Benniston AC, Harriman A. Photocatalysis and self-catalyzed photobleaching with covalently-linked chromophore-quencher conjugates built around BOPHY. Photochemical and Photobiological Sciences 2018, 17(6), 750-762.
- Benniston AC, Tkachenko NV, Lemmetyinen H, He X. Charge Shift, Charge Recombination and Triplet Formation in a Closely-Spaced Molecular Dyad based on a Borondipyrromethene (Bodipy) and an Expanded Acridinium Cation. ChemPhotoChem 2018, 2(3), 277-282.
- Al-Aqar R, Benniston AC, Harriman A, Perks T. Structural Dynamics and Barrier Crossing Observed for a Fluorescent O-Doped Polycyclic Aromatic Hydrocarbon. ChemPhotoChem 2017, 1(5), 198-205.
- Arauzo A, Bartolomé E, Benniston AC, Melnic S, Shova S, Luzón J, Alonso PJ, Barra AL, Bartolomé J. Slow Magnetic Relaxation in a dimeric Mn2Ca2 complex enabled by the large Mn(III) rhombicity. Dalton Transactions 2017, 46(3), 720-732.
- Sirbu D, Benniston AC, Harriman A. One-Pot Synthesis of a Mono-O,B,N-strapped BODIPY Derivative Displaying Bright Fluorescence in the Solid State. Organic Letters 2017, 19(7), 1626-1629.
- Sirbu D, Butcher JB, Waddell PG, Andras P, Benniston AC. Locally Excited State – Charge Transfer State Coupled Dyes as Optically Responsive Neuron Firing Probes. Chemistry - A European Journal 2017, 23(58), 14639-14649.
- Melnic S, Shova S, Benniston AC, Waddell P. Evolution of Manganese-Calcium Cluster Structures based on Nitrogen and Oxygen Donor Ligands. CrystEngComm 2017, 19, 3674-3681.
- Arranja C, Aguiar A, Encarnação T, Fonseca S, Justino L, Castro R, Benniston AC, Harriman A, Burrows H, Sobrala AJFN. Double-tailed Long Chain BODIPYs - Synthesis, Characterization and Preliminary Studies on their use as Lipid Fluorescence Probes. Journal of Molecular Structure 2017, 1146, 62.
- Al-Aqar R, Atahan A, Benniston AC, Perks T, Waddell PG, Harriman A. Exciton Migration and Surface Trapping for a Photonic Crystal Displaying Charge-Recombination Fluorescence. Chemistry: A European Journal 2016, 22(43), 15420-15429.
- Farras P, Waller H, Benniston AC. Enhanced Photostability of a Ruthenium(II) Polypyridyl Complex under Highly Oxidizing Aqueous Conditions by its Partial Inclusion into a Cyclodextrin. Chemistry-A European Journal 2016, 22(3), 1133-1140.
- Hedley GJ, Ruseckas A, Benniston AC, Harriman A, Samuel IDW. Ultrafast Electronic Energy Transfer Beyond the Weak Coupling Limit in a Proximal but Orthogonal Molecular Dyad. Journal of Physical Chemistry A 2015, 119(51), 12665-12671.
- Sirbu D, Turta C, Gibson EA, Benniston AC. The ferrocene effect: enhanced electrocatalytic hydrogen production using meso-tetraferrocenyl porphyrin palladium (II) and copper (II) complexes. Dalton Transactions 2015, 44(33), 14646-14655.
- He X, Benniston AC, Saarenpää H, Lemmetyinen H, Tkachenko NV, Baisch U. Polymorph Crystal Packing Effects on Charge Transfer Emission in the Solid State. Chemical Science 2015, 6(6), 3525-3532.
- Marin I, Turta C, Benniston AC, Harrington RW, Clegg W. Homoleptic and Heteroleptic Ruthenium(II) Complexes based on 2,6-bis(quinolin-2-yl)pyridine Ligands: Multiple Charged State Modules for Potential Density Memory Storage. European Journal of Inorganic Chemistry 2015, (5), 786-793.
- Al-Aqar R, Avis D, Benniston AC, Harriman A. The Quest for Highly Fluorescent Chromophores: Evaluation of 1H,3H-Isochromeno[6,5,4-mna]xanthene-1,3-dione (CXD). RSC Advances 2014, 4(95), 53072-53078.
- Benniston AC, Sirbu D, Turta C, Probert MR, Clegg W. Synthesis, Molecular Structure and Properties of a Ferrocene-based Difluoropyrrolo-oxaborole Derivative. European Journal of Inorganic Chemistry 2014, 2014(36), 6212-6219.
- Voda I, Turta C, Lozan V, Benniston AC, Baisch U. Synthesis of a zinc(II) cage-like structure based on 1,4-bis((1H-imidazoyl-1-yl)methyl)benzene and 5-sulfoisophthalic acid. Polyhedron 2014, 67, 301-305.
- Sirbu D, Turta C, Benniston AC, Lemmetyinen H, Tkachenko NV, Wood C, Gibson E. Synthesis and properties of a meso- tris–ferrocene appended zinc(II) porphyrin and a critical evaluation of its dye sensitised solar cell (DSSC) performance. RSC Advances 2014, 4(43), 22733-22742.
- Bai D, Benniston AC, Tkachenko NV, Lemmetyinen H, Whittle V. ROFRET: A Molecular-Scale Fluorescent Probe Displaying Viscosity Enhanced Intramolecular Förster Energy Transfer. ChemPhysChem 2014, 15(14), 3089-3096.
- Benniston AC, Melnic S, Turta C, Arauzo AB, Bartolomé J, Bartolomé E, Harrington RW, Probert MR. Preparation and Properties of a Calcium(II)-based Molecular Chain Decorated with Manganese(II) Butterfly-like Complexes. Dalton Transations 2014, 43(35), 13349-13357.
- Bai D, Benniston AC, Clift S, Baisch U, Steyn J, Everitt N, Andras P. Low molecular weight Neutral Boron Dipyrromethene (Bodipy) dyads for fluorescence-based neural imaging. Journal of Molecular Structure 2014, 1065-1066, 10-15.
- Benniston AC, Sirbu D, Turta C, Probert MR, Clegg W. ChemInform Abstract: A Simple Method for Desymmetrizing 1,1′‐Ferrocenedicarboxaldehyde. ChemInform: selected abstracts in chemistry 2014, 45(49).
- Farràs P, Benniston AC. Bodipy-ruthenium(II) tris-Bipyridyl Dyads for Homogeneous Photochemical Oxidations. Tetrahedron Letters 2014, 55(51), 7011-7014.
- Lerrick RI, Winstanley TPL, Haggerty K, Wills C, Clegg W, Harrington RW, Bultinck P, Herrebout W, Benniston AC, Hall MJ. Axially Chiral BODIPYs. Chemical Communications 2014, 50(36), 4714-4716.
- Benniston AC, Sirbu D, Turta C, Probert MR, Clegg W. A simple method for desymmetrizing 1,1′-ferrocenedicarboxaldehyde. Tetrahedron Letters 2014, 55(28), 3777-3780.
- Bai D, Benniston AC, Hagon J, Lemmetyinen H, Tkachenko NV, Harrington RW. Tuning the Forster overlap integral: energy transfer over 20 Angstroms from a pyrene-based donor to borondipyrromethene (Bodipy). Physical Chemistry Chemical Physics 2013, 15(24), 9854-9861.
- Benniston AC, Yang SJ, Lemmetyinen H, Tkachenko NV. Complexation Enhanced Excited-State Deactivation by Lithium Ion Coordination to a Borondipyrromethene (Bodipy) Donor-Bridge-Acceptor Dyad. European Journal of Organic Chemistry 2013, 2013(30), 6859-6869.
- Benniston AC, He XY, Lemmetyinen H, Tkachenko NV. Charge transfer properties of a donor-acceptor dyad based on an expanded acridinium cation. RSC Advances 2013, 3(15), 4995-5002.
- Alamiry MAH, Benniston AC, Hagon J, Winstanley TPL, Lemmetyinen H, Tkachenko NV. The fluorine effect: photophysical properties of borondipyrromethene (bodipy) dyes appended at the meso position with fluorinated aryl groups. RSC Advances 2012, 2(11), 4944-4950.
- Benniston AC, Hagon J, He XY, Yang SJ, Harrington RW. Spring Open Two-plus-Two Electron Storage in a Disulfide-Strapped Methyl Viologen Derivative. Organic Letters 2012, 14(2), 506-509.
- Benniston AC, Hagon J, He XY, Lemmetyinen H, Tkachenko NV, Clegg W, Harrington RW. Photoinduced charge shift and charge recombination through an alkynyl spacer for an expanded acridinium-based dyad. Physical Chemistry Chemical Physics 2012, 14(9), 3194-3199.
- Benniston AC, Winstanley TPL, Lemmetyinen H, Tkachenko NV, Harrington RW, Wills C. Large Stokes Shift Fluorescent Dyes Based on a Highly Substituted Terephthalic Acid Core. Organic Letters 2012, 14(6), 1374-1377.
- Alamiry MAH, Benniston AC, Copley G, Harriman A. Freezing and glass transition phenomena for 1,2-dichloroethane under high pressure as revealed by fluorescence spectroscopy. RSC Advances 2012, 2(5), 1936-1941.
- Bai D, Benniston AC, Hagon J, Lemmetyinen H, Tkachenko NV, Clegg W, Harrington RW. Exploring Forster electronic energy transfer in a decoupled anthracenyl-based borondipyrromethene (bodipy) dyad. Physical Chemistry Chemical Physics 2012, 14(13), 4447-4456.
- Benniston AC, Clift S, Hagon J, Lemmetyinen H, Tkachenko NV, Clegg W, Harrington RW. Effect on Charge Transfer and Charge Recombination by Insertion of a Naphthalene-Based Bridge in Molecular Dyads Based on Borondipyrromethene (Bodipy). ChemPhysChem 2012, 13(16), 3672-3681.
- Alamiry MAH, Benniston AC, Harriman A. Effect of Pressure on the Solubilization of a Fluorescent Merocyanine Dye by a Nonionic Surfactant. Journal of Physical Chemistry Part B 2012, 116(1), 253-260.
- Yucel B, Sanli B, Akbulut H, Ozbey S, Benniston AC. Colour-Responsive Fluorescent Oxy Radical Sensors. Organic & Biomolecular Chemistry 2012, 10(9), 1775-1784.
- Jun T, Kim K, Lee KM, Benniston AC, Churchill DG. Meso-thienyl and furyl rotor effects in BF2-chelated dipyrrin dyes: solution spectroscopic studies and X-ray structural packing analysis of isomer and congener effects. Journal of Coordination Chemistry 2012, 65(24), 4299-4314.
- Benniston AC, Copley G, Harriman A, Ryan R. Thermoresponsive Fluorescent Polymers based on a Quaterthiophene-containing Boron dipyrromethene (Bodipy) Dyad Dispersed in Silicone Rubber. Journal of Materials Chemistry 2011, 21(8), 2601-2608.
- Alamiry MAH, Benniston AC, Copley G, Harriman A, Howgego D. Intramolecular Excimer Formation for Covalently Linked Boron Dipyrromethene Dyes. Journal of Physical Chemistry A 2011, 115(44), 12111-12119.
- Benniston AC, Clift S, Harriman A. Intramolecular Charge-transfer Interactions in a Julolidine-Bodipy Molecular Dyad as Revealed by 13C NMR Chemical Shifts. Journal of Molecular Structure 2011, 985(2-3), 346-354.
- Benniston AC, Harriman A, Yang S, Harrington RW. Highly-Strained Cyclophanes Bearing Both Photo- and Electro-Active Constituents. Tetrahedron Letters 2011, 52(41), 5315-5318.
- Benniston AC, Bunn A. Sulfonation of Phenalenone Revisited: Preparation and Characterisation of Sodium 1H-Phenalene-1-one-5-sulfonate. Journal of Chemical Research 2010, 34(11), 603-605.
- Benniston AC, Copley G, Lemmetyinen H, Tkachenko NV. Off the Back or on the Side: Comparison of meso and 2-Substituted Donor-Acceptor Difluoroborondipyrromethene (Bodipy) Dyads. European Journal of Organic Chemistry 2010, 2010(15), 2867-2877.
- Benniston AC, Harriman A, Whittle VL, Zelzer M. Molecular Rotors Based on the Boron Dipyrromethene Fluorophore. European Journal of Organic Chemistry 2010, (3), 523-530.
- Benniston AC, Harriman A, Whittle VL, Zelzer M, Harrington RW, Clegg W. Exciplex-like emission from a closely-spaced, orthogonally-sited anthracenyl-boron dipyrromethene (Bodipy) molecular dyad. Photochemical and Photobiological Sciences 2010, 9(7), 1009-1017.
- Benniston AC, Copley G, Lemmetyinen H, Tkachenko NV. Exciplex Formation and Excited State Deactivation of Difluoroborondipyrromethene (Bodipy) Dyads. ChemPhysChem 2010, 11(8), 1685-1692.
- Benniston AC, Copley G, Harriman A, Howgego D, Harrington RW, Clegg W. Cofacial Boron Dipyrromethene (Bodipy) Dimers: Synthesis, Charge Delocalization, and Exciton Coupling. Journal of Organic Chemistry 2010, 75(6), 2018-2027.
- Benniston AC, Harriman A, Li PY. Bidirectional Electron Transfer in Molecular Tetrads. Journal of the American Chemical Society 2010, 132(1), 26-27.
- Benniston AC, Elliott KJ, Harrington RW, Clegg W. On the Photochemical Stability of the 9-Mesityl-10-methylacridinium Cation. European Journal of Organic Chemistry 2009, (2), 253-258.
- Benniston AC, Allen BD, Harriman A, Llarena I, Rostron JP, Stewart B. Accessing molecular memory via a disulfide switch. New Journal of Chemistry 2009, 33(2), 417-427.
- Benniston AC, Fortage J. Selenospiropyrans incorporating appended pyrene chromophores. Tetrahedron Letters 2008, 49(27), 4292-4295.
- Benniston AC, Copley G, Elliott KJ, Harrington RW, Clegg W. Redox-controlled fluorescence modulation in a BODIPY-quinone dyad. European Journal of Organic Chemistry 2008, -(16), 2705-2713.
- Benniston AC, Harriman A, Li P, Patel PV, Sams CA. Electron Exchange in Conformationally Restricted Donor–Spacer–Acceptor Dyads: Angle Dependence and Involvement of Upper-Lying Excited States. Chemistry: A European Journal 2008, 14(6), 1710-1717.
- Alamiry MAH, Benniston AC, Copley G, Elliott KJ, Harriman A, Stewart B, Zhi Y-G. A Molecular Rotor Based on an Unhindered Boron Dipyrromethene (Bodipy) Dye. Chemistry of Materials 2008, 20(12), 4024-4032.
- Benniston AC, Copley G, Harriman A, Rewinska DB, Harrington RW, Clegg W. A donor-acceptor molecular dyad showing multiple electronic energy-transfer processes in crystalline and amorphous states. Journal of the American Chemical Society 2008, 130(23), 7174-7175.
- Lydon DP, Li P, Benniston AC, McFarlane W, Harrington RW, Clegg W. Solid phase and solution phase structural characterization of pyrene-based, T-shaped molecular dyads. European Journal of Organic Chemistry 2007, (10), 1653-1658.
- Benniston AC, Harriman A, Howell SL, Li P, Lydon DP. Opening a spiropyran ring by way of an exciplex intermediate. Journal of Organic Chemistry 2007, 72(3), 888-897.
- Benniston AC, Harriman A, Rewinska DB, Yang S, Zhi Y-G. On the conjugation length for oligo(ethynylnaphthalene)-based molecular rods. Chemistry - A European Journal 2007, 13(36), 10194-10203.
- Benniston AC, Harriman A, Howell SL, Sams CA, Zhi Y-G. Intramolecular excimer formation and delayed fluorescence in sterically constrained pyrene dimers. Chemistry - A European Journal 2007, 13(16), 4665-4674.
- Benniston AC, Harriman A, Llarena I, Sams CA. Intramolecular Delayed Fluorescence as a Tool for Imaging Science: Synthesis and Photophysical Properties of a First-Generation Emitter. Chemistry of Materials 2007, 19(8), 1931.
- Benniston AC, Harriman A, Llarena I, Sams CA. Intramolecular delayed fluorescence as a tool for imaging science: Synthesis and photophysical properties of a first-generation emitter. Chemistry of Materials 2007, 19(8), 1931-1938.
- Allen BD, Benniston AC, Harriman A, Llarena I, Sams CA. How the central torsion angle affects the rates of nonradiative decay in some geometrically restricted p-quaterphenyls. Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment and General Theory 2007, 111(14), 2641-2649.
- Benniston AC, Harriman A, Pariani C, Sams CA. Competition between energy transfer and interligand electron transfer in porphyrin - Osmium(II) Bis(2,2′:6′,2″-terpyridine) dyads. Journal of Physical Chemistry A 2007, 111(37), 8918-8924.
- Benniston AC, Harriman A, Li P, Rostron JP, Harrington RW, Clegg W. A spectroscopic study of the reduction of geometrically restrained viologens. Chemistry - A European Journal 2007, 13(28), 7838-7851.
- Llarena I, Benniston AC, Izzet G, Rewinska DB, Harrington RW, Clegg W. Synthesis of a redox-active molecular switch based on dibenzo[1,2]dithiine. Tetrahedron Letters 2006, 47(51), 9135-9138.
- Benniston AC, Rewinska DB. Simultaneous fluorescence and redox modulation in an irreversible photochrome based on a strained dibenzo-acridinium cation. Organic and Biomolecular Chemistry 2006, 4(21), 3886-3888.
- Benniston AC, Chapman GM, Harriman A, Sams CA. Photophysical investigation of the triplet manifold of mono- and bis-phenylethynyl-(2,2′:6′,2″-terpyridine) ruthenium(II) complexes. Inorganica Chimica Acta 2006, 359(3), 753-758.
- Benniston AC, Harriman A, Pariani C, Sams CA. Intramolecular energy-transfer processes in a bis(porphyrin)-ruthenium(II) bis(2,2′:6′,2″-terpyridine) molecular array. Physical Chemistry Chemical Physics 2006, 8(17), 2051-2057.
- Allen BD, Benniston AC, Harriman A, Mallon LJ, Pariani C. Competing through-space and through-bond, intramolecular triplet-energy transfer in a supposedly rigid ruthenium(II) tris(2,2′-bipyridine)- fullerene molecular dyad. Physical Chemistry Chemical Physics 2006, 8(35), 4112-4118.
- Benniston AC, Harriman A, Li P, Patel PV, Rostron JP, Sams CA. An apparent angle dependence for the nonradiative deactivation of excited triplet states of sterically constrained, binuclear ruthenium(II) bis(2,2′:6′,2″-terpyridine) complexes. Journal of Physical Chemistry A 2006, 110(32), 9880-9886.
- Benniston AC, Harriman A, Li P, Patel PV, Sams CA. A strategy for the synthesis of metal bis(2,2′:6′,2″- terpyridine)-terminated molecular dyads having controlled torsion angles at the central biphenyl linker. Journal of Organic Chemistry 2006, 71(9), 3481-3493.
- Allen BD, Benniston AC, Harriman A, Rostron SA, Yu C. The photophysical properties of a julolidene-based molecular rotor. Physical Chemistry Chemical Physics 2005, 7(16), 3035-3040.
- Benniston AC, Harriman A, Li P, Patel PV, Sams CA. The effect of torsion angle on the rate of intramolecular triplet energy transfer. Physical Chemistry Chemical Physics 2005, 7(21), 3677-3679.
- Benniston AC, Harriman A, Rostron JP. The effect of solvent polarity on the photophysical properties of 4-cyano-(4′-methylthio)diphenylacetylene: A prototypic donor-acceptor system. Physical Chemistry Chemical Physics 2005, 7(16), 3041-3047.
- Benniston AC, Harriman A, Li P, Sams CA. Temperature-induced switching of the mechanism for intramolecular energy transfer in a 2,2′:6′,2″-terpyridine-based Ru(II)-Os(II) trinuclear array. Journal of the American Chemical Society 2005, 127(8), 2553-2564.
- Benniston AC, Gunning P, Peacock RD. Synthesis and binding properties of hybrid cyclophane - Azamacrocyclic receptors. Journal of Organic Chemistry 2005, 70(1), 115-123.
- Benniston AC, Chapman GM, Harriman A, Rostron SA. Reversible luminescence switching in a ruthenium(II) Bis(2,2′: 6′,2″-terpyridine)-benzoquinone dyad. Inorganic Chemistry 2005, 44(11), 4029-4036.
- Verhoeven JW, van Ramesdonk HJ, Zhang H, Groeneveld MM, Benniston AC, Harriman A. Long-lived charge-transfer states in 9-Aryl-Acridinium ions: a critical reinvestigation. International Journal of Photoenergy 2005, 7(2), 103-108.
- Benniston AC, Harriman A, Li P, Rostron JP, Verhoeven JW. Illumination of the 9-mesityl-10-methylacridinium ion does not give a long-lived photoredox state. Chemical Communications 2005, (21), 2701-2703.
- Benniston AC, Harriman A, Li P, Rostron JP, Verhoeven JW. Illumination of the 9-mesityl-10-methylacridinium ion does not give a long-lived photoredox state. Chemical Communications 2005, (21), 2701-2703.
- Benniston AC, Harriman A, Lawrie DJ, Mehrabi M. DNA binding of a molecular-scale receptor in the presence of zinc(II) ions. European Journal of Organic Chemistry 2005, (7), 1384-1391.
- Benniston AC, Harriman A, Li P, Rostron JP. Controlling electron delocalisation in constrained N,N′-dimethyl-4, 4′-bipyridinium dications. Tetrahedron Letters 2005, 46(43), 7291-7293.
- Benniston AC, Harriman A, Li P, Sams CA. Comparison of the photophysical properties of osmium(II) Bis(2,2′:6′,2″-terpyridine) and the corresponding ethynylated derivative. Journal of Physical Chemistry A 2005, 109(10), 2302-2309.
- Benniston AC, Harriman A, Li P, Rostron JP, Van Ramesdonk HJ, Groeneveld MM, Zhang H, Verhoeven JW. Charge shift and triplet state formation in the 9-mesityl-10- methylacridinium cation. Journal of the American Chemical Society 2005, 127(46), 16054-16064.
- Benniston AC, Harriman A, Patel PV, Sams CA. A strategy for controlling the central torsion angle in biphenyl-based molecular-scale bridges. European Journal of Organic Chemistry 2005, 2005(21), 4680-4686.
- Gunning P, Benniston AC, Peacock R. A Modular Ditopic Crown-Shielded Phosphate Ion-Pair Receptor. ChemInform 2005, 36(10), 2226.
- Benniston AC, Harriman A, Lawrie DJ, Mehrabi M, Russell OD. A ditopic receptor for cation binding and facilitated transport through a supported liquid membrane. Inorganica Chimica Acta 2005, 358(12), 3483-3490.
- Benniston AC, Harriman A, Lawrie DJ, Mayeux A. The photophysical properties of a pyrene-thiophene-terpyridine conjugate and of its zinc(II) and ruthenium(II) complexes. Physical Chemistry Chemical Physics 2004, 6(1), 51-57.
- Benniston AC, Mitchell S, Rostron SA, Yang SJ. Synthesis of extended ethynylnaphthalene-based ruthenium(II) 2,2′:6′,2″-terpyridine complexes. Tetrahedron Letters 2004, 45(42), 7883-7885.
- Benniston AC, Harriman A, Lawrie DJ, Rostron SA. Synthesis of a multitopic pyrene-thiophene-anthracene-2,2′:6′, 2″-terpyridine array. Tetrahedron Letters 2004, 45(12), 2503-2506.
- Benniston AC, Clegg W, Harrington RW, Li P. Sterically Constrained bis(2,2’:6’,2’’-Terpyridine) Ligand. Acta Crystallographica, Section E: Structure Reports Online 2004, E60(12), 02452.
- Benniston AC, Grosshenny V, Harriman A, Ziessel R. Photophysical properties of closely-coupled, binuclear ruthenium(II) bis(2,2′:6′,2′-terpyridine) complexes. Dalton Transactions 2004, (8), 1227-1232.
- Benniston AC, Harriman A, McCulloch IE, Mehrabi M, Rostron SA, Sams CA. Photophysical properties of an extended bis-oxonol dye. Journal of Photochemistry and Photobiology A: Chemistry 2004, 163(1-2), 61-67.
- Benniston AC, Harriman A, Mehrabi M, Rostran S, McCulloch IE, Sams C. Photophysical Properties of a Bis-Oxonol Dye. Journal of Photochemistry and Photobiology A: Chemistry 2004, 163(1-2), 61-67.
- Benniston AC, Harriman A, Li PY, Sams CA, Ward MD. Orientational control of electronic coupling in mixed-valence, binuclear ruthenium(II)-bis(2,2 ': 6 ',2 ''-terpyridine) complexes. Journal of the American Chemical Society 2004, 126(42), 13630-13631.
- Benniston AC, Chapman GM, Harriman A, Mehrabi M. Intramolecular energy transfer in molecular dyads comprising free-base porphyrin and ruthenium(II) bis(2,2′:6′,2″-terpyridine) termini. Journal of Physical Chemistry A 2004, 108(42), 9026-9036.
- Benniston AC, Chapman G, Harriman A, Mehrabi M, Sams CA. Electron delocalization in a ruthenium(II) bis(2,2′:6′, 2″-terpyridyl) complex. Inorganic Chemistry 2004, 43(14), 4227-4233.
- Benniston AC, Harriman A, Romero FM, Ziessel R. Effect of the parent ligand on the photophysical properties of closely-coupled, binuclear ruthenium(II) tris(2,2′-bipyridine) complexes. Dalton Transactions 2004, (8), 1233-1238.
- Benniston AC, Harriman A, Li P, Sams CA. Conformational control of electron delocalisation in geometrically- constrained, binuclear ruthenium(II) bis(2,2′:6′,2″- terpyridine) complexes. Physical Chemistry Chemical Physics 2004, 6(5), 875-877.
- Benniston AC, Clegg W, Harrington RW, Li P. A sterically constrained bis(2,2′:6′,2″-terpyridine) ligand. Acta Crystallographica Section E: Structure Reports Online 2004, 60(12), o2452-o2454.
- Gunning P, Benniston AC, Peacock RD. A modular ditopic crown-shielded phosphate ion-pair receptor. Chemical Communications 2004, (19), 2226-2227.
- Benniston AC, Harriman A, Lawrie DJ, Rostron SA. A Closely-Coupled Pyrene Dimer Having Unusually Intense Fluorescence. European Journal of Organic Chemistry 2004, 2004(10), 2272-2276.
- Amini A, Bates K, Benniston AC, Lawrie DJ, Soubeyrand-Lenoir E. Towards molecular T-junction relays. Tetrahedron Letters 2003, 44(45), 8245-8247.
- Benniston AC, Clegg W, Harriman A, Harrington RW, Li P, Sams C. Synthesis of a biphenyl-based cyclophane via benzidine rearrangement of a constrained m-nitrophenol derivative. Tetrahedron Letters 2003, 44(13), 2665-2667.
- Benniston AC, Davies M, Harriman A, Sams C. Photophysical properties of a supramolecular interlocked conjugate. Journal of Physical Chemistry A 2003, 107(23), 4669-4675.
- Benniston AC, Matousek P, McCulloch IE, Parker AW, Towrie M. Detailed picosecond Kerr-gated time-resolved resonance Raman spectroscopy and time-resolved emission studies of merocyanine 540 in various solvents. Journal of Physical Chemistry A 2003, 107(22), 4347-4353.
- Benniston AC, Li P, Sams C. Controlling the torsion angle via adventitious cation binding. Tetrahedron Letters 2003, 44(20), 3947-3949.
- Benniston AC, Harriman A, Li P, Sams CA. Building molecular-scale bridges having restricted rotation. Tetrahedron Letters 2003, 44(22), 4167-4169.
- Benniston AC, Harriman A, Lawrie DJ, Mayeux A, Rafferty K, Russell OD. A general purpose reporter for cations: Absorption, fluorescence and electrochemical sensing of zinc(II). Dalton Transactions 2003, (24), 4762-4769.
- Benniston AC, Ellis D, Farrugia LJ, Kennedy R, Peacock RD, Walker S. The synthesis of small azamacrocycles bearing pendant aromatic functionalities. The crystal structures of [Cu(L-1)(2)](PF6)(2), [(L-1)CuCl2], [Cu(L-6)(NO3)(2)] and [Cu-2(L-7-H)(2)(OH2)(2)](PF6)(2)center dot 3H(2)O (L-1 = N-(mesitylethyl)-1,4,7-triazacyclononane, L-6 = N-(4-hydroxymethylbenzyl)-1,4,7-triazacylcononane, L-7 = N-(4-benzylcarboxylic acid)-1,4,7-triazacylcononane). Polyhedron 2002, 21(3), 333-342.
- Benniston AC, Ellis D, Farrugia LJ, Kennedy R, Peacock RD, Walker S. The synthesis of small azamacrocycles bearing pendant aromatic functionalities. Polyhedron 2002, 21(3), 333-342.
- Benniston AC, Mackie PR, Farrugia LJ, Smith G, Teat SJ, McLean AJ. Detailed Photophysical Properties of a Functionalized Ruthenium(II) Polypyridyl Complex: Through-Space Solvent Effects. New Journal of Chemistry 2001, 2001(25), 458-464.
- Benniston AC, Gardner S, Farrugia LJ, Harriman A. Structure and photophysical properties of constrained donor-acceptor [2]catenanes bearing an appended secondary donor. Journal of Chemical Research 2000, 2000(8), 360-361.
- Benniston AC, Mackie PR, Farrugia LJ, Mallinson P, Clegg W, Teat S. Properties and single-crystal X-ray structure of Bis[3,3″-bis(4-methylphenyl)-2,2′:6′,2″-terpyridine]iron(II) hexafluorophosphate–acetonitrile–diisopropyl ether (1/1.5/1). Australian Journal of Chemistry 2000, 53(8), 707-713.
- Benniston AC, Farrugia LJ, Mackie PR, Mallinson P, Clegg W, Teat SJ. Properties and single-crystal X-ray structure of bis[3,3″-bis(4-methylphenyl)-2,2′:6′,2″-terpyridine] iron(II) hexafluorophosphate-acetonitrile-diisopropyl ether (1/1.5/1). Australian Journal of Chemistry 2000, 53(8), 707-713.
- Benniston AC, Matousek P, Parker AW. Kerr-gated picosecond time-resolved resonance Raman spectroscopic probing of the excited states in Λ-[Ru(bipy)2dppz](BF4)2 (bipy = 2,2′-bipyridyl, dppz = dipyrido[3,2-a :2′,3′-c ]phenazine). Journa of Raman Spectroscopy 2000, 31(6), 503-507.
- Harriman A, Khatyr A, Ziessel R, Benniston AC. An Unusually Shallow Distance-Dependence for Triplet-Energy Transfer. Angewandte Chemie International Edition 2000, 39(23), 4287-4290.
- Harriman A, Khatyr A, Ziessel R, Benniston AC. An unusually shallow distance-dependence for triplet-energy transfer. Angewandte Chemie - International Edition 2000, 39(23), 4287-4290.
- A. Harriman, F. M. Romero, R. Ziessel, A. C. Benniston. Triplet Energy Transfer within Closely-spaced Positional Isomers of Ru/Os Polypyridine-based Heterodyads. J. Phys. Chem 1999, 103, 5399.
- Benniston AC, Yufit DS, Howard JAK. Bis(hydrazinium) 4-hydroxy-1-oxo-2H-phthalazine-6,7-dicarboxylate. Acta Crystallographica. Section C: Crystal Structure Communications 1999, 55(9), 1535.
- A. C. Benniston, A. Harriman. Photoisomerization of a Sterically-constrained Merocyanine Dye. J. Chem. Soc., Faraday Trans 1998, 94, 1841.
- A. C. Benniston, P. R. Mackie, L. J. Farrugia, S. Parsons, W. Clegg, S. J. Teat. Metallo-based Cyclophanes and [2]Catenanes: Towards Molecular-Scale Functional Assemblies. Platinum Metals Review 1998, 42, 100.
- A. C. Benniston, A. Harriman, C. McAvoy. Effect of Resonance Polarity on the Rate of Isomerization for Merocyanine Dyes. J. Chem. Soc., Faraday Trans 1998, 94, 519.
- A. C. Benniston, P. R. Mackie, A. Harriman. Artificial Photosynthesis: Mimicking Redox Asymmetry. Angew. Chem. Int. Ed 1998, 37, 354.
- A. C. Benniston, K. S. Gulliya, A. Harriman. Spin-Orbital Coupling Effects on the Photophysical Properties and Phototoxicity of Merocyanine Dyes. J. Chem. Soc., Faraday Trans 1997, 93, 2491.
- A. C. Benniston, A. Harriman, C. McAvoy. Photoisomerization of Sterically Hindered Merocyanine Dyes. J. Chem. Soc., Faraday Trans 1997, 93, 3653.
- A. C. Benniston, V. Grosshenny, A. Harriman, R. Ziessel. Effect of Hybridisation on the Electronic Properties of Carbon Bridges. New J. Chem 1997, 21, 405.
- A. C. Benniston. Building off the back of Chelators: Synthesis of 3,3”-bis(4-methylphenyl)-2,2’:6’,2”-Terpyridine. Tetrahedron Lett 1997, 38, 8279.
- A. C. Benniston, A. Harriman, D. S. Yufit. Artificial Phototropism: Reversible Photodissociation of Self-Assembled Interlocking Conjugates. Angew. Chem. Int. Ed 1997, 36, 2356.
- A. C. Benniston, D. S. Yufit, P. R. Mackie. A p-Stacked Complex Between 4,4’-Dimethyl-4,4’-Bipyridinium Bis(hexafluorophosphate) and 1,5-Bis (Hydroxyethoxy)ethoxy-naphthalene. Acta Cryst. C 1997, C53, 1899.
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Book Chapters
- Sirbu D, Straistari T, Benniston AC. 5: Hydrogenases: From Biomimetic to Bioinspired Models. In: Marius Reglier, ed. Bioinspired Chemistry: From Enzymes to Synthetic Models. Singapore: World Scientific Publishing, 2019, pp.89-121.
- Benniston AC. Cyclophanes: Endobasic, Endoacidic and Endolipophilic Cavities. In: Encyclopedia of Supramolecular Chemistry. Boca Raton, Florida, USA: CRC press, 2004.
- Benniston AC, Mackie PR. Functional Nanostructures Incorporating Responsive Modules. In: H. S. Nalwa, ed. Handbook of Nanostructured Materials and Nanotechnology: Concise Edition. London: Wiley & Sons, 2001, pp.693.
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Conference Proceedings (inc. Abstracts)
- Benniston AC. Electron transfer in molecular dyads and tetrads. In: 240th American Chemical Society National Meeting. 2010, Boston, Massachusetts, USA: American Chemical Society.
- Benniston AC, Harriman A. Controlling electron exchange in molecular assemblies. In: Coordination Chemistry Reviews: 17th International Symposium on Photochemistry and Photophysics of Coordination Compounds. 2008, Dublin, Ireland: Elsevier.
- Gunning PT, Peacock RD, Benniston AC. Creating shielded metal ion reaction centres. In: 226th National Meeting of the American Chemical Society. 2003, New York, USA: American Chemical Society.
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Notes
- Choo YSL, Giamberini M, Reina JA, Waddell PG, Benniston AC. Erratum: Functionalized fluorescent terephthalate monomers and their attempted polyester formation. Organic and Biomolecular Chemistry 2020, 18(45), 9316-9316.
- Benniston AC, Harriman A, Verhoeven JW. Comment: Electron-transfer reactions in the 9-mesityl-10-methylacridinium ion: Impurities, triplet states and infinitely long-lived charge-shift states?. Physical Chemistry Chemical Physics 2008, 10(33), 5156-5158.
- Benniston AC. Porphyrin linked poly(pyridyl)-based conjugates as artificial photosynthetic reaction centre models. Physical Chemistry Chemical Physics 2007, 9(43), 5739-5747.
- Verhoeven JW, Van Ramesdonk HJ, Groeneveld MM, Benniston AC, Harriman A. Long-lived charge-transfer states in compact donor-acceptor dyads. ChemPhysChem 2005, 6(11), 2251-2260.
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Report
- Benniston AC, Melnic S, Sirbu D, Waddell PG. CCDC 1900500: Experimental Crystal Structure Determination. 2019. CSD Communications.
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Reviews
- Benniston AC, Copley G. Lighting the way ahead with boron dipyrromethene (Bodipy) dyes. Physical Chemistry Chemical Physics 2009, 11(21), 4124-4131.
- Benniston AC, Harriman A. Controlling electron exchange in molecular assemblies. Coordination Chemistry Reviews 2008, 252(23-24), 2528-2539.
- Benniston AC, Harriman A. Artificial photosynthesis. Materials Today 2008, 11(12), 26-34.
- Benniston AC, Harriman A. Charge on the move: How electron-transfer dynamics depend on molecular conformation. Chemical Society Reviews 2006, 35(2), 169-179.
- Benniston AC. Pushing around electrons: Towards 2-D and 3-D molecular switches. Chemical Society Reviews 2004, 33(9), 573-578.