Staff Profile
Professor Mark Geoghegan
Roland Cookson Professor of Engineering Materials
- Telephone: 01912087110
- Personal Website: http://www.markgeoghegan.org
- Address: Merz Court
Claremont Road
Newcastle-upon-Tyne
NE1 7RU
Background
Introduction
Mark Geoghegan joined Newcastle University in 2019 from the University of Sheffield, where he was previously Professor of Soft Matter Physics in the Department of Physics and Astronomy. His research interests focus on different aspects of soft matter and materials research. This includes polymer films, polymer diffusion, organic electronics, biomaterials, adhesion, and soft nanotechnology. He has written one text book on Polymer Electronics with Professor Georges Hadziioannou of the University of Bordeaux.
ORCID
0000-0001-9919-7357
Qualifications
MA (Oxon) MSc (B'ham) PhD Cantab
Fellow of the Institute of Physics (FInstP) and Fellow of the Royal Society of Chemistry (FRSC)
Roles and Responsibilities
School Athena SWAN Champion
Research
My research interests include:
- Diffusion in polymer systems: Diffusion of polymers on surfaces and in solution.
- Physics of polymer networks: Polymer networks swell up in suitable solvents, but try to regain their original shape when the solvent is removed. How do we engineer networks or gels to have appropriate chemical, physical, and mechanical properties,
- Stability, creation and structure of polymer films: How and why do thin polymer films break up, and can we control their behaviour? Can we understand and optimise the structure of films of polymer mixtures? How do films form?
- Semiconducting polymers: How does the structure of an organic electronic device influence its properties?
- Polyelectrolyte brushes: These materials show large changes in their physical properties depending upon the pH of the solution they are in contact with. Can we use these to perform useful tasks?
- Adhesion: The creation of polymeric reversible adhesive systems and the mechanisms behind bioadhesion
- Nanotribology: What controls the contact mechanics and adhesive behaviour of polymer films? Can these be optimised
- Biological systems: The measurement of cellular adhesion. What controls the interactions between biomolecules?
Teaching
CME8118 Material Stability
CME2028 Thermodynamics 2
Publications
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Articles
- Sierra-Romero A, Novakovic K, Geoghegan M. A reversible water-based electrostatic adhesive. Angewandte Chemie - International Edition 2024, 63(2), e202310750.
- Novakovic K, Thumbarathy D, Peeters M, Geoghegan M, Go Jefferies J, Hicks C, Manika D, Dai S. Zero-waste circular economy of plastic packaging: The bottlenecks and a way forward. Sustainable Materials and Technologies 2023, 38, e00735.
- Petroli A, Petroli M, Romagnoli M, Geoghegan M. Determination of the rate-dependent adhesion of polydimethylsiloxane using an atomic force microscope. Polymer 2022, 262, 125445.
- Morales-García AL, Walton R, Blakeman JT, Banwart SA, Harding JH, Geoghegan M, Freeman CL, Rolfe SA. The role of extracellular DNA in microbial attachment to oxidized silicon surfaces in the presence of Ca2+ and Na+. Langmuir 2021, 37(32), 9838-9850.
- Geoghegan M, Mróz MM, Botta C, Parrenin L, Brochon C, Cloutet E, Pavlopoulou E, Hadziioannou G, Virgili T. Optical gain in semiconducting polymer nano and mesoparticles. Molecules 2021, 26(4), 1138.
- Mears M, Zhang ZJ, Jackson RCD, Si Y, Bradford TJB, Torkelson JM, Geoghegan M. Lateral diffusion of single poly(ethylene oxide) chains on the surfaces of glassy and molten polymer films. Journal of Chemical Physics 2021, 154(16), 164902.
- Hafner A, Gutfreund P, Toperverg BP, Jones AOF, de Silva JP, Wildes A, Fischer HE, Geoghegan M, Sferrazza M. Combined specular and off-specular reflectometry: elucidating the complex structure of soft buried interfaces. Journal of Applied Crystallography 2021, 54(3), 924-948.
- Hafner A, Gutfreund P, Toperverg BP, Geoghegan M, Sferrazza M. 2D Reflectometry for the investigation of polymer interfaces: off-specular neutron scattering. Journal of Physics: Condensed Matter 2021, 33(36), 364002.
- Hall AR, Blakeman JT, Eissa AM, Chapman P, Morales-García AL, Stennett L, Martin O, Giraud E, Dockrell DH, Cameron NR, Wiese M, Yakob Y, Rogers ME, Geoghegan M. Glycan-glycan interactions determine Leishmania attachment to the midgut of permissive sand fly vectors. Chemical Science 2020, 11(40), 10973-10983.
- Seddon WD, Alfhaid L, Dunbar ADF, Geoghegan M, Williams NH. Adhesion of grafted-to polyelectrolyte brushes functionalized with calix[4]resorcinarene and deposited as a monolayer. Langmuir 2020, 36(46), 13843-13852.
- Alfhaid L, Williams NH, Geoghegan M. Adhesion between oppositely charged polyelectrolytes in salt solution. Journal of Applied Polymer Science 2020, 137(38), e49130.
- Clarkson CG, Johnson A, Leggett GJ, Geoghegan M. Slow polymer diffusion on brush-patterned surfaces in aqueous solution. Nanoscale 2019, 11(13), 6052-6061.
- Virgili T, Botta C, Mroz MM, Parrenin L, Brochon C, Cloutet E, Pavlopoulou E, Hadziioannou G, Geoghegan M. Size-dependent photophysical behavior of low bandgap semiconducting polymer particles. Frontiers in Chemistry 2019, 7, 409.
- Blakeman JT, Morales-Garcia AL, Mukherjee J, Gori K, Hayward AS, Lant NJ, Geoghegan M. Extracellular DNA Provides Structural Integrity to a Micrococcus luteus Biofilm. Langmuir 2019, 35(19), 6468-6475.
- Kennelly TM, Li Y, Cao Y, Qwarnstrom EE, Geoghegan M. Distinct Binding Interactions of α5β1-Integrin and Proteoglycans with Fibronectin. Biophysical Journal 2019, 117(4), 688-695.
- Mouhamad Y, Mokarian-Tabari P, Jones RAL, Geoghegan M. Application of mean-field theory to the spin casting of polystyrene and poly(methyl methacrylate) blend films from toluene. Polymer 2019, 178, 121578.
- Al-Baradi AM, Rimmer S, Carter SR, De Silva JP, King SM, Maccarini M, Farago B, Noirez L, Geoghegan M. Temperature-dependent structure and dynamics of highly-branched poly(N -isopropylacrylamide) in aqueous solution. Soft Matter 2018, 14(8), 1482-1491.
- Canning SL, Ferner JMF, Mangham NM, Wear TJ, Reynolds SW, Morgan J, Fairclough JPA, King SM, Swift T, Geoghegan M, Rimmer S. Highly-ordered onion micelles made from amphiphilic highly-branched copolymers. Polymer Chemistry 2018, 9(47), 5617-5629.
- Zhang ZJ, Edmondson S, Mears M, Madsen J, Armes SP, Leggett GJ, Geoghegan M. Blob Size Controls Diffusion of Free Polymer in a Chemically Identical Brush in Semidilute Solution. Macromolecules 2018, 51(16), 6312-6317.
- Alfhaid L, La Spina R, Tomlinson MR, Hall AR, Seddon WD, Williams NH, Cousin F, Gorb S, Geoghegan M. Adhesion between oppositely charged polyelectrolytes. Journal of Adhesion 2018, 94(1), 58-76.
- Geoghegan M. The swelling of weak polyelectrolytes at low salt concentrations in dilute solution. Polymer 2017, 112, 414-417.
- Raftari M, Zhang ZJ, Carter SR, Leggett GJ, Geoghegan M. Salt Dependence of the Tribological Properties of a Surface-Grafted Weak Polycation in Aqueous Solution. Tribology Letters 2017, 66(1), 11.
- Zhang ZJ, Moxey M, Alswieleh A, Armes SP, Lewis AL, Geoghegan M, Leggett GJ. Nanotribological investigation of polymer brushes with lithographically defined and systematically varying grafting densities. Langmuir 2017, 33(3), 706-713.
- Zhang ZJ, Madsen J, Warren NJ, Mears M, Leggett GJ, Lewis AL, Geoghegan M. Influence of salt on the solution dynamics of a phosphorylcholine-based polyzwitterion. European Polymer Journal 2017, 87, 449-457.
- Baker JA, Mouhamad Y, Hooper KEA, Burkitt D, Geoghegan M, Watson TM. From spin coating to roll-to-roll: Investigating the challenge of upscaling lead halide perovskite solar cells. IET Renewable Power Generation 2017, 11(5), 546-549.
- Di Lauro M, Casalini S, Berto M, Campana A, Cramer T, Murgia M, Geoghegan M, Bortolotti CA, Biscarini F. The Substrate is a pH-Controlled Second Gate of Electrolyte-Gated Organic Field-Effect Transistor. ACS Applied Materials and Interfaces 2016, 8(46), 31783-31790.
- Swift T, Swanson L, Geoghegan M, Rimmer S. The pH-responsive behaviour of poly(acrylic acid) in aqueous solution is dependent on molar mass. Soft Matter 2016, 12(9), 2542-2549.
- Zhang Z, Moxey M, Alswieleh A, Morse AJ, Lewis AL, Geoghegan M, Leggett GJ. Effect of Salt on Phosphorylcholine-based Zwitterionic Polymer Brushes. Langmuir 2016, 32(20), 5048-5057.
- Alfhaid L, Seddon WD, Williams NH, Geoghegan M. Double-network hydrogels improve pH-switchable adhesion. Soft Matter 2016, 12(22), 5022-5028.
- Raftari M, Zhang ZJ, Carter SR, Leggett GJ, Geoghegan M. Nanoscale Contact Mechanics between Two Grafted Polyelectrolyte Surfaces. Macromolecules 2015, 48(17), 6272-6279.
- James D, Higgins AM, Rees P, Geoghegan M, Brown MR, Chang S-S, Mon D, Cubitt R, Dalgliesh R, Gutfreund P. Measurement of molecular mixing at a conjugated polymer interface by specular and off-specular neutron scattering. Soft Matter 2015, 11(48), 9393-9403.
- Pen Y, Zhang ZJ, Morales-Garcia AL, Mears M, Tarmey DS, Edyvean RG, Banwart SA, Geoghegan M. Effect of extracellular polymeric substances on the mechanical properties of Rhodococcus. Biochimica et Biophysica Acta - Biomembranes 2015, 1848(2), 518-526.
- Al-Baradi A, Tomlinson MR, Zhang ZJ, Geoghegan M. Determination of the molar mass of surface-grafted weak polyelectrolyte brushes using force spectroscopy. Polymer 2015, 67, 111-117.
- Clarkson CG, Lovett JR, Madsen J, Armes SP, Geoghegan M. Characterization of diblock copolymer order-order transitions in semidilute aqueous solution using fluorescence correlation spectroscopy. Macromolecular Rapid Communications 2015, 36(17), 1572-1577.
- Mears M, Kennelly TM, Howse JR, Tarmey DS, Geoghegan M, Pacey AA. Reduced curvilinear velocity of boar sperm on substrates with increased hydrophobicity. Theriogenology 2014, 81(5), 764-769.
- Raftari M, Zhang Z, Carter SR, Leggett GJ, Geoghegan M. Frictional properties of a polycationic brush. Soft Matter 2014, 10(16), 2759-2766.
- Mouhamad Y, Mokarian-Tabari P, Clarke N, Jones RAL, Geoghegan M. Dynamics of polymer film formation during spin coating. Journal of Applied Physics 2014, 116(12), 123513.
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Reviews
- Geoghegan M. Weak polyelectrolyte brushes. Soft Matter 2022, 18(13), 2500-2511.
- Sierra-Romero A, Novakovic K, Geoghegan M. Adhesive Interfaces toward a Zero-Waste Industry. Langmuir 2022, 38(50), 15476-15493.
- Hall AR, Geoghegan M. Polymers and biopolymers at interfaces. Reports on Progress in Physics 2018, 81(3), 036601.