Module Catalogue 2024/25

Pre Requisite Comment

N/A

Co Requisite Comment

N/A

Aims

This module builds on the foundation of stage 1 physical chemistry and gives a deeper understanding of the principles that govern chemical processes. The module covers microscopic theories of chemistry based on quantum mechanics, the macroscopic point of view of thermodynamics, the molecular view of reactive collisions, and the statistical concepts that link these three branches of the subject. The principles of chemical energetics, kinetics and spectroscopy will be illustrated throughout with examples of the modern applications of physical chemistry.

Outline Of Syllabus

Foundations and Applications in Quantum Mechanics

Fundamentals in Quantum Mechanics (e.g. Particle-in-a-box model)
Time-dependent and Time-independent Quantum Mechanics
Applying Quantum Mechanics: Quantum Chemistry
Quantum Chemistry in Materials Discovery
Understanding and Computing Excited State Properties of Molecules

Energetics and Interfacial Phenomena

Statistical Concepts, Chemical Potential and Thermodynamics of Solutions
Standard States, Activities and Electrode Potentials
Fundamentals in Interfaces: Adsorption, Isotherms and Electrical Double Layer
Colloids and Polymers
Applications of Thermodynamics in Energy Materials and Sustainability

Molecules in Motion

Kinetic theory, Molecular Mobility and Collisions in Gases
Electrolyte Conductivity and Ion Mobility in Solution
Diffusion-Controlled Reactions and Transition State Theory
Excited State Kinetics
Complex Reaction Mechanisms

Intended Knowledge Outcomes

At the end of the module a student will be able to:

• understand thermodynamics and statistical mechanics, with special emphasis on solutions and interfaces
• understand the principles of quantum chemistry and spectroscopy
• understand chemical kinetics and related time-dependent phenomena
• be familiar with modern applications of physical chemistry

Intended Skill Outcomes

At the end of the module a student will be able to:

• Solve problems by drawing on physico-chemical principles and making appropriate calculations
• Apply basic equations and solve more advanced (than Stage 1) numerical problems in chemical kinetics,
thermodynamics, statistical mechanics, quantum theory and spectroscopy.

Teaching Rationale And Relationship

A variety of methods will be used for delivery of the material and to ensure that students actively engage with the subject matter. Traditional lecture delivery is accompanied by calculation classes.

Each lecturer will be available for drop-in sessions where students can have queries clarified.

Assessment Rationale And Relationship

The formative digital exam will assess the level of knowledge and understanding from topics studied in semester 1. This will allow the module team to review and feedback on any topic which may have been problematic.

The online computer assessment tests students ability to perform calculations and solve unseen problems in the absence of the time pressure of a conventional written examination.

The summative written examination will assess the level of knowledge and understanding of all aspects of the module. The examination will present students with questions from a selection of topics learnt throughout semester 1 and 2 module content.

General Notes

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