Staff Profile
Dr Erli Lu
NU Academic Track Fellow (NUAcT)
- Email: erli.lu@ncl.ac.uk
- Telephone: 0191 208 4511
- Address: 2.26 Bedson Buidling
Newcastle University.
Newcastle upon Tyne, UK.
NE1 7RU
I joined Newcastle University in September 2019 as a NUAcT Fellow. Previously, I obtained a PhD in rare-earth metal chemistry in January 2012, from Shanghai Institute of Organic Chemistry (SIOC), Chinese Academy of Sciences (CAS), under the supervision of Prof. Yaofeng Chen. After Shanghai, initially supported by an EU Marie Curie International Incoming Fellowship, I worked at Universities of Nottingham (06.2012 - 10.2015) and Manchester (10.2015-09.2019) as a postdoctoral researcher, in the group of Prof. Steve Liddle, investigating actinide metal chemistry.
At Newcastle, my group investigates alkali metal chemistry in unconventional environments.
Alkali metals (AMs: Li, Na, K, Rb, Cs) are ubiquitous elements and have widespread technical applications in batteries, pharmaceutical and food industries. Alkali metal chemistry provides textbook examples at A-level, GCSE and university levels. The state-of-the-art alkali metal chemistry has been dominated by 1 oxidation state.
My research aims at systematically expanding alkali metal chemistry into new and unconventional oxidation states, i.e. 0 and -1, for the first time in over hundreds of years. The AM(0/-1) complexes will have novel structural properties and reactivity, such as inert small molecule activation (e.g. N2 activation). Furthermore, the AM(0) complexes may provide new insights into the Li-battery process, and suggest new avenues to tackle a grand challenge in the Li-battery industry: Li-metal deposition.
Another frontier of my research is using unconventional alkali metal chemistry to develop novel electron-storage materials and investigate their applications in energy storage.
- Lu E, Atkinson BE, Wooles AJ, Boronski JT, Doyle LR, Tuna F, Cryer JD, Cobb PJ, Vitorica-Yrezabal IJ, Whitehead GFS, Kaltsoyannis N, Liddle ST. Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(v)–dinitrogen complex. Nature Chemistry 2019, 11(9), 806-811.
- Lu E, Sajjad S, Berryman VEJ, Wooles AJ, Kaltsoyannis N, Liddle ST. Emergence of the structure-directing role of f-orbital overlap-driven covalency. Nature Communications 2019, 10(1), 634.
- Hu S-X, Lu E, Liddle ST. Prediction of high bond-order metal-metal multiple-bonds in heterobimetallic 3d-4f/5f complexes [TM-M{N(: o-[NCH2P(CH3)2]C6H4)3}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd). Dalton Transactions 2019, 48(34), 12867-12879.
- Du J, King DM, Chatelain L, Lu E, Tuna F, McInnes EJL, Wooles AJ, Maron L, Liddle ST. Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides. Chemical Science 2019, 10(13), 3738-3745.
- Magnall R, Balazs G, Lu E, Tuna F, Wooles AJ, Scheer M, Liddle ST. Trapping of a Highly Bent and Reduced Form of 2-Phosphaethynolate in a Mixed-Valence Diuranium–Triamidoamine Complex. Angewandte Chemie - International Edition 2019, 58(30), 10215-10219.
- Lu E, Wooles AJ, Gregson M, Cobb PJ, Liddle ST. A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double-Dative Bonding Character. Angewandte Chemie International Edition 2018, 57(22), 6587-6591.
- Lu E, Chu J, Chen Y. Scandium Terminal Imido Chemistry. Accounts of Chemical Research 2018, 51(2), 557-566.
- Lu E, Boronski JT, Gregson M, Wooles AJ, Liddle ST. Silyl-Phosphino-Carbene Complexes of Uranium(IV). Angewandte Chemie International Edition 2018, 57(19), 5506-5511.
- Gardner BM, Kefalidis CE, Lu E, Patel D, McInnes EJL, Tuna F, Wooles AJ, Maron L, Liddle ST. Evidence for single metal two electron oxidative addition and reductive elimination at uranium. Nature Communications 2017, 8(1), 1898.
- Han X, Xiang L, Lamsfus CA, Mao W, Lu E, Maron L, Leng X, Chen Y. Synthesis and Reactivity of a Scandium Terminal Hydride: H2 Activation by a Scandium Terminal Imido Complex. Chemistry - A European Journal 2017, 23(59), 14728-14732.
- Gregson M, Lu E, Mills DP, Tuna F, McInnes EJL, Hennig C, Scheinost AC, McMaster J, Lewis W, Blake AJ, Kerridge A, Liddle ST. The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes. Nature Communications 2017, 8, 14137.
- Gregson M, Lu E, Tuna F, McInnes EJL, Hennig C, Scheinost AC, McMaster J, Lewis W, Blake AJ, Kerridge A, Liddle ST. Emergence of comparable covalency in isostructural cerium(IV)- and uranium(IV)-carbon multiple bonds. Chemical Science 2016, 7(5), 3286-3297.
- Lu E, Tuna F, Lewis W, Kaltsoyannis N, Liddle ST. Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR’ Units (R=Ph2PNSiMe3; R’=CPh3): Alkali-Metal-Mediated Push–Pull Effects with an Amido Auxiliary. Chemistry - A European Journal 2016, 22(33), 11554-11558.
- Lu E, Cooper OJ, Tuna F, Wooles AJ, Kaltsoyannis N, Liddle ST. Uranium–Carbene–Imido Metalla-Allenes: Ancillary-Ligand-Controlled cis-/trans-Isomerisation and Assessment of trans Influence in the R2C=UIV=NR’ Unit (R=Ph2PNSiMe3; R’=CPh3). Chemistry - A European Journal 2016, 22(33), 11559-11563.
- Lu E, Liddle ST. Group 10 Metal-Metal Bonds. In: Stephen T. Liddle, ed. Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties. Wiley‐VCH Verlag GmbH & Co. KGaA, 2015, pp.325-395.
- Poineau F, Sattelberger AP, Lu E, Liddle ST. Group 7 Metal-Metal Bonds. In: Stephen T. Liddle, ed. Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties. Wiley‐VCH Verlag GmbH & Co. KGaA, 2015, pp.175-224.
- Lu E, Liddle ST. Uranium-mediated oxidative addition and reductive elimination. Dalton Transactions 2015, 44(29), 12924-12941.
- Lu E, Cooper OJ, McMaster J, Tuna F, McInnes EJL, Lewis W, Blake AJ, Liddle ST. Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex. Angewandte Chemie - International Edition 2014, 53(26), 6696-6700.
- Lu E, Lewis W, Blake AJ, Liddle ST. The ketimide ligand is not just an inert spectator: Heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex. Angewandte Chemie - International Edition 2014, 53(35), 9356-9359.