Staff Profile
Dr Nick Walker
Degree Programme Director (Undergraduate Programmes in Chemistry); Senior Lecturer
- Personal Website: http://www.staff.ncl.ac.uk/nick.walker
- Address: Room 2.64, Bedson Building.
School of Chemistry,
Bedson Building,
Newcastle upon Tyne
Tyne and Wear
NE1 7RU
I pursued undergraduate and postgraduate degrees at the University of Sussex completing a D.Phil under the guidance of Anthony J. Stace in 1999. I held postdoctoral appointments in Canada and the United States before moving to the University of Bristol to perform independent research whilst funded by a Royal Society University Research Fellowship in 2003. I received the Meldola Medal and Prize of the Royal Society of Chemistry during the same year. An ESPRC grant enabled me to construct the first example of a chirped-pulse Fourier transform microwave spectrometer in the U.K. in 2010. This spectrometer is equipped with a laser ablation source to allow the study of novel metal-containing molecules.
I moved to Newcastle University for a lectureship in Physical Chemistry in March 2012 and received a European Research Council Starting Investigator Award in November of the same year. I aim to use and apply the new instrumentation available for microwave spectroscopy to tackle problems which lie outside the traditional boundaries of the field.
I have served on the Faraday Division Council of the Royal Society of Chemistry (RSC); as Chair of the Newcastle-upon-Tyne and North-East Coast local section of the RSC from 2017 until 2019; and am a member of the Molecular Physics group committee of the Institute of Physics.
Areas of Expertise: Physical Chemistry; Molecular Spectroscopy and Dynamics.
Introduction
Spectroscopy exploits the emission, absorption and scattering of electromagnetic radiation for the study of molecules and materials. Emission at microwave frequencies (between 3 and 300 GHz) is associated with transitions between rotational energy levels in molecules which, in turn, depend sensitively on details of molecular structure. My research applies microwave spectroscopy to quantify fundamental molecular interactions which have broad significance throughout many areas of chemistry and biology.
Current Activities
I maintain and operate a chirped-pulse, FTMW (Fourier transform microwave) spectrometer which allows the acquisition of broadband microwave spectra. This globally-unique instrument is equipped with a laser ablation source that allows the generation and study of metal-containing complexes. Broadband rotational spectroscopy allows for the detection and assignment of spectra in a fraction of the time that would be required using any of the previous generation of spectrometers. I collaborate with researchers drawn from around the world to apply our instrumentation to important problems in molecular structure determination. The nature of hydrogen bonding interactions between water and heteroaromatic rings such as thiazole and imidazole are a focus of current research.
Teaching
Duties at Newcastle University include;
Degree Programme Director for Undergraduate Programmes in Chemistry. Responsible for student-facing aspects of programme administration including degree programme changes (between different undergraduate degrees in Chemistry), study adjustments (in response to student circumstances), student communications (about teaching, induction, timetabling, assessment and the student experience).
NES1404 (Introductory Physical Chemistry) - Lectures in "Spectroscopy"
NES1406 (General Chemistry) - Coordinate innovative online assessment and feedback delivered using NUMBAS
NES2400 and NES3400 (Physical Chemistry) - Laboratory Course Demonstrator
NES8405 (Chemistry Far From Equilibrium)- Lectures in "Astrochemistry"
Final Year Undergraduate Project student supervisor
Personal Tutor
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Articles
- Gupta S, Cummings CN, Walker NR, Arunan E. Microwave Spectroscopic and Computational Analyses of the Phenylacetylene···Methanol Complex: Insights into Intermolecular Interactions. Physical Chemistry: Chemical Physics 2024, Epub ahead of print.
- Cummings CN, Walker NR. Hydrogen Bonding and Molecular Geometry in Isolated Hydrates of 2-Ethylthiazole Characterised by Microwave Spectroscopy. ChemPhysChem 2024, 25(8), e202400011.
- Welch R, Marshall MD, Gougoula E, Walker NR, Leung HO. Geometry of the Argon¼Imidazole Complex Revealed by the Microwave Spectra of Four Isotopologues. Journal of Molecular Spectroscopy 2024, 405, 111948.
- Antonelli E, Gougoula E, Walker NR, Schwell M, Nguyen HVL, Kleiner I. A global rho-axis method for fitting asymmetric tops with one methyl internal rotor and two 14N nuclei: Application of BELGI-2N to the microwave spectra of four methylimidazole isomers. The Journal of Chemical Physics 2024, 160, 214309.
- Cummings CN, Kleiner I, Walker NR. Noncovalent Interactions in the Molecular Geometries of 4‑Methylthiazole···H2O and 5‑Methylthiazole···H2O Revealed byMicrowave Spectroscopy. Journal of Physical Chemistry A 2023, 127(39), 8133-8145.
- Gougoula E, Cummings CN, Xu Y, Lu T, Feng G, Walker NR. Cooperative hydrogen bonding in thiazole⋯(H2O)2 revealed by microwave spectroscopy. Journal of Chemical Physics 2023, 158, 114307.
- Gougoula E, Cummings CN, Medcraft C, Heitkamper J, Walker NR. Microwave Spectra, Molecular Geometries, and Internal Rotation of CH3 in N-methylimidazole...¼H2O and 2-methylimidazole...¼H2O Complexes. Physical Chemistry Chemical Physics 2022, 24(20), 12354-12362.
- Gougoula E, Cole DJ, Walker NR. Bifunctional Hydrogen Bonding of Imidazole with Water Explored by Rotational Spectroscopy and DFT Calculations. Journal of Physical Chemistry A 2020, 124(13), 2649-2659.
- Das A, Mandal PK, Lovas FJ, Medcraft C, Walker NR, Arunan E. The H2S Dimer is Hydrogen-Bonded: Direct Confirmation from Microwave Spectroscopy. Angewandte Chemie: International Edition 2018, 57(46), 15199-15203.
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Letter
- Song W, Maris A, Cummings CN, Evangelisti L, Walker NR, Melandri S. The Challenging Conformational Landscape of Cysteamine···H2O Revealed by the Strong Interplay of Rotational Spectroscopy and Quantum Chemical Calculations. Journal of Physical Chemistry Letters 2024, 15(40), 10054–10061.